[N,N′-Di-tert-butyl-P,P-diphenylphosphinimidic Amidato-κN,κN′]chlorosilicon-κSi-tetracarbonyliron
نویسندگان
چکیده
The title complex {[Ph2P(tBuN)2](Cl)Si:->Fe(CO)4} (2) was synthesized via the reaction of chlorosilylene [Ph2P(tBuN)2]SiCl (1), supported by an iminophosphonamide ligand with Fe(CO)5 in THF. molecular structure 2 fully characterized NMR (1H, 13C, 29Si, and 31P) IR spectroscopies, as well single-crystal X-ray diffraction (SCXRD) analysis. In SCXRD analysis 2, silylene located axial positions coordination sphere central iron atom other sites were occupied carbonyl ligands.
منابع مشابه
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ژورنال
عنوان ژورنال: Molbank
سال: 2022
ISSN: ['1422-8599']
DOI: https://doi.org/10.3390/m1433